What are the other color curves? Have they been applied to your image also?
./curves.sh -s 250,255 -g C "0,18 31,19 64,62 86,100 110,139 124,159 142,181 161,200 194,223" wedding.jpg weddingtest7.jpg
This set of break points does not seem to match what you have in PS curves diagram. The last break point on your curve is higher than x=194 (out of 255). It looks at something very close but slightly less than x=255. Also I am not sure why you restricted my curves script to x=250. To match PS you would need to use -s 255,255.
I note that the only odd thing is that in your break points, you do not go all the way to x=255 (or even 250). When I do that in my PS, it leave a straight horizontal line. Thus in your case it would extend from 194,223 with a straight line going to 255,223 rather than splining between those two points. My script will add 255,255 automatically and will spline all the points. So there will be some difference between the two. I do not know if that is enough to make the difference you are seeing.
My old PS CS does not have the SHOW options in the panel. I understand the histogram option shows the histogram. I am not sure what the Channel Overlays option does?
I will have to experiment, but only with break points that contain 0,0 and 255,255 and see if I see any substantial difference between PS and my curves.